Product ID:AUTOCOAT LV MM TONER 331EC 005036-1115303
MSDS Date:04/27/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLJWP

AKZO NOBEL COATINGS INC

5555 SPALDING DR
NORCROSS, GA 30092
US

Emergency Phone: 800-424-9300;613-996-6666 (CANUTEC)

Info Phone: 770-441-8628

Preparer: AKZO CAR REFINISH MFG DPT

Cage: AKZNB

AKZO NOBEL COATINGS LTD.

ETOBICOKE, ONTARIO, M9W5S6, ON 30092 CN

Telephone: UNK

Cage: TO942

N.AV, LD50 (ORAL, RAT)

OSHA PEL N.AV.

ACGIH TLV: 100 PPM

8.0, LD50 (ORAL, RAT)

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 710 MG/M3;150 PPM

ACGIH TLV: 713 MG/M3;150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

3500

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 435 MG/M3;100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.1, LD50 (ORAL,

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2.1, LD50 (ORAL,RAT)

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

2.0, LD50 (ORAL,RAT)

CAS: 8052-41-3

RTECS: WJ8925000

OSHA PEL 2900 MG/M3;500 PPM

ACGIH TLV: 525 MG/M3;100 PPM

636 MG/M3,

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL SEE TABLE Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N.

CAS: 7429-90-5

RTECS: BD0330000

OSHA PEL 10 MG/M3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRIMARY ROUTES OF ENTRY: INHALATION,
SKIN CONTACT, INGESTION, EYES. ACUTE: INHALATION: NASAL & RESP
IRRIT, NAUSEA, COUGH, DIZZINESS, WEAKNESS, HEADACHE, DROWSINESS,
FATIGUE, CHEST PAIN, VOMITING, CNS EFFECTS, ASPHYXIATION, LACK OF
COORDINATION. SKIN CONTACT: EXTRACTION OF NATURAL OILS WITH
RESULTING DRY SKIN, IRRIT, REDNESS & DERMATITIS. CAN BE ABSORBED
THROUGH THE SKIN INTO THE BLOOD. EYE:: IRRIT ATION, REDNESS, PAIN,
BLURRED VISION, SENSATION OF SEEING HALOS AROUND LIGHTS &
REVERSIBLE DAMAGE. INGESTION: GI IRRITATION, NAUSEA, VOMITING,
DIARRHEA, DROWSINESS, LACK OF COORDINATION, CNS EFFECTS,
DEPRESSION (OVEREXPOSURE)
Explanation of Carcinogenicity:ETHYLBENZENE: IARC GROUP 2B (POSSIBLY
CARCINOGENIC TO HUMANS), VOLUME 77, PAGE 227, 2000.
Effects of Overexposure:HEALTH HAZARD (CON'T): CHRONIC: REPEATED
OVEREXPOSURE MAY CAUSE CNS DAMAGE, KIDNEY DAMAGE, LIVER
ABNORMALITIES, LUNG DAMAGE, REPRODUCTIVE ORGAN DAMAGE, BLOOD
EFFECTS, DERMATITIS. OTHER HEALTH EFFECTS : INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL OR
FATAL. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAI N & NERVOUS SYSTEM
DAMAGE. TOLUENE APPEARS ON NAVY LIST OF OCCUPATIONAL CHEMICAL
REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH
PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING &
EXPOSURE INFORMATION .
Medical Cond Aggravated by Exposure:SKIN DISORDERS, LIVER CONDITIONS,
KIDNEY CONDITIONS, NEUROLOGICAL DISORDERS, PREGNANCY, REPRODUCTIVE
SYSTEM DISORDERS.

First Aid:IN ALL CASES IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
INHALATION: MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING, WASH WITH
SOAP AND WATER OR RECOGNIZED SKIN CLEANER. DO NOT USE SOLVENTS OR
THINNERS. EYE CONTACT: CONTACT LENSES MUST BE REMOVED, FLUSH WITH
WATER FOR AT LEAST 15 MINUTES, CONSULT A PHYSICIAN IMMEDIATELY.
INGESTION: DRINK ON E OR TWO GLASSES OF WATER TO DILUTE. DO NOT
INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point Method:SCC
Flash Point:=26.7C, 80.F
80-92F (27-33C).
Lower Limits:0.9
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG OR
SPRAY. WATER JET OR STREAM IS UNSUITABLE. NFPA 704: HEALTH-2,
FLAMMABILITY-2, REACTIVITY-0.
Fire Fighting Procedures:WATER SHOULD BE USED TO COOL CONTAINERS
EXPOSED TO FIRE. FIRE FIGHTING PERSONNEL SHOULD WEAR NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT .
NFPA FLAMMABILITY/C LASS: 1C. FLAMMABLE LIQUID, REFER TO GUIDE 127
OF THE NORTH AMERICAN EMERGENCY GUIDE BOOK. PRODUCT USE: COLOR
COAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. FIRE WILL PRODUCE DENSE BLACK SMOKE
CONTAINING HAZARDOUS PRODUCTS OF COMBUSTION. SYMPTOMS MAY NOT BE
IMMEDIATELY APPARENT. OBTAIN MEDICAL AT TN. FORMS EXPLOSIVE MIXTURE
WITH AIR. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF
IGNITION AND FLASH BACK.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS, VENTILATE CONFINED AREA. DIKE TO REDUCE EXTENT OF
SPILL. REMOVE WITH INERT ABSORBENT (VERMICULITE, CLAY, OIL-DRY,
KITTY LITER, ETC) USING NON-SP ARKING TOOLS.TRANSFER TO A GROUNDED
METAL CONTAINER, SEAL CONTAINER. DISPOSE OF AS HAZARDOUS WASTE. IF
NECESSARY REPORT TO APPLICABLE GOVERNMENT AGENCY.

Handling and Storage Precautions:USE APPROVED BONDING & GROUNDING
PROCEDURES WHEN TRANSFERRING LIQUID TO ANOTHER CONTAINER. DO NOT
TRANSFER TO UNLABELED CONTAINERS. NO SMOKING. STORE PLASTIC CNTNRS
OF FLAMMABLE LIQUIDS INSIDE CLOSED APPROVED BOXES OR SAFETY
CABINETS. STORE CNTNRS OUT OF SUN, AWAY FROM HEAT, SPARKS & (OTHER
PREC)
Other Precautions:HNDLG/STOR (CONT): OPEN FLAMES. CLOSE ALL CONTAINERS
AFTER EACH USE. CONSULT NFPA & LOCAL CODES FOR MORE STORAGE
REQUIREMENTS. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG FLOOR.
USE EXPLOSION PROOF EQUIP IN AREA WHERE THERE IS SPRAYING/OPEN
CONTAINERS. DO NOT TAKE INTERNALLY. OBSERVE LABEL PRECAU
TIONS.(OTHER INFO)

Respiratory Protection:WHEN PERSONNEL, WHETHER SPRAYING OR NOT, ARE
INSIDE SPRAY BOOTH, VENTILATION IS UNLIKELY TO BE SUFFICIENT TO
CONTROL PARTICULATES & CHEM VAPOR IN ALL CASES. IN SUCH CASES NIOSH
APPROVED AIR SUPPLIED R ESP EQUIPMENT RECOMMENDED UNTIL PARTICULATE
& VAPOR CONC HAS FALLEN BELOW EXPOSURE LIMITS. IF MONITORING
DEMONSTRATES LEVEL BELOW TLV/PEL WEAR(OTHER PROT EQUIP)
Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP VAPOR CONCENTRATIONS
BELOW GIVEN TLV &/OR PEL. FOR BAKING FINISHES, EXHAUST VAPORS
EMITTED DURING HEATING. (SUPP SAFETY)
Protective Gloves:REQ'D FOR PROLONGED REPEATED CONTACT. USE SOLVENT
RESISTANT GLOVES.(STATE REGS)
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD .
Other Protective Equipment:ANTI STATIC PAINT SUIT. EYEWASH AND DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA . RESP PROT (CONT): NIOSH
APPROVED RESPIRATOR DEVICE. SEE SAFETY EQUIP SUPPLIER FOR
RECOMMENDATION & (HYGIENE PRAC)
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING THE
WASHROOM. LAUNDER CLOTHING BEFORE REUSE. OTHER PROT EQUIP (CONT):
EVALUATION &. WEAR ORGANIC VAPOR CARTRIDGE RESP WHEN HANDLING.
Supplemental Safety and Health
VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG FLOORS. MATERIAL HAS
OFFENSIVE ODOR. PROLONGED EXPOS MAY REDUCE THE USER'S SENSITIVITY
TO THE ODOR, THUS REDUCING EFFECTIVENESS OF ODOR AS A WARNING AGA
INST EXPOSURE. VENTILATION (CONT): REMOVE DECOMP PROD FORMED
DURING WELDING/FLAME CUTTING OF SURFACES COATED W/PROD.

Boiling Pt:=93.3C, 200.F
B.P. Text:RANGE: 200-380F (93-19
Vapor Density:> AIR.
Spec Gravity:0.97 - 1.54.
VOC Grams/Liter:3.
Evaporation Rate & Reference:SLOWER THAN ETHER.
Appearance and Odor:COLORED LIQUID. ORGANIC ODOR.
Percent Volatiles by Volume:40 - 42.5

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ALKALI METALS, HYDROGEN FLUORIDE, NITRIC ACID, SODIUM
HYDROXIDE.
Stability Condition to Avoid:HEAT, OPEN FLAMES, SPARKS. WASTE DISPOSAL
(CONT): WHEN DISCARDED IN ITS SUPPLIED FORM, PRODUCT MEETS HAZARD
CRITERIA OF 'IGNITABILITY' & MUST BE CONSIDERED AS HAZARDOUS WASTE
D001.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, VARIOUS
HYDROCARBONS, TOXIC FUMES.

Waste Disposal Methods:DISPOSE IAW FEDERAL, STATE, PROVINCIAL & LOCAL
POLLUTION REQUIREMENTS. IN ADDITION, RAGS, SPRAY BOOTH FILTERS,
PAINT SUITS, EMPTY CANS, ETC., CONTAMINATED WITH PRODUCT MAY BE
HAZARDOUS WASTE. DETERMIN E WHETHER CONTAMINATED ITEMS ARE
HAZARDOUS & DISPOSE OF AS APPROPRIATE. CLEAN PREFERABLY W/DETERGENT
, AVOID USING SOLVENTS. (CONDITIONS TO AVOID)

Toxicological Information:CARCINOGENICITY: THIS PRODUCT CONTAINS
ETHYLBENZENE. A DRAFT REPORT ON A STUDY CONDUCTED BY THE NTP
STATES THAT LIFETIME INHALATION EXPOSURE OF RATS & MICE TO
CONCENTRATIONS OF ETHYLBENZENE (750 PPM) RESULTED IN INCREASES IN
CERTAIN TYPES OF CANCER, INCLUDING KIDNEY TUMORS IN RATS & LUNG &
LIVER TUMORS IN MICE. THESE EFFECTS WERE NOT OBSERVED IN ANIMALS
EXPOSED TO LOWER CONCENTRATIONS OF ETHYLBEN ZENE (75 PPM OR 250
PPM). THE DRAFT REPORT DOES NOT ADDRESS THE RELEVANCE OF THESE
RESULTS TO HUMANS. SENSITIZATION: THIS PRODUCT MAY CAUSE SKIN &
INHALATION SENSITIZATION TO CERTAIN INDIVIDUALS. TERA TOGENICITY:
NONE KNOWN. (STATE REG)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:GENERAL INFORMATION: AVOID RUNOFF INTO GROUND, STORMS OR
SEWERS WHICH LEAD INTO WATERWAYS. WATER RUNOFF CAN CAUSE
ENVIRONMENTAL DAMAGE. ENVIRONMENTAL IMPACT DATA (PERCENTAGE BY
WEIGHT): N/P. VOC: SEE PHYSICAL/CHEMICAL. OZONE DEPLETORS: NONE.
HEAVY METALS: NONE. US FEDERAL HAZARDOUS AIR POLLUTANTS: XYLENE,
ETHYLBENZENE. SEE INDIVIDUAL COMPOSITIONS. THERE ARE EXTENSIVE
ECOLOGICAL DATA AVAILABLE ON THE VARIOUS COMPONENTS OF THIS
PRODUCT. AN ADEQUATE REPRESENTATION OF ALL THESE DATA IS BEYOND THE
SCOPE OF THIS DOCUMENT. PLEASE CONTACT THE INFORMATION PHONE
NUMBER.

Transport Information:GROUND SHIPMENTS: FOR INNER CONTAINERS OF 5L OR
LESS USE ONLY PROPER AKZO NOBEL OR UN SPECIFIED OUTER CONTAINERS.
POSITIVELY CLOSE ALL SEAMS. SHIPPER MUST BE TRAINED & CERTIFIED TO
HANDLE HAZARDOUS MA TERIALS IN GROUND TRANSPORTATION (DOT/TDG). FOR
CONTAINERS GREATER THAN 5L USE 1A1 CONTAINERS. PROPER SHIPPING
NAME: PAINT. HAZARD CLASS/DIVISION: 3. UN IDENTIFICATION #: UN1263.
PACKAGING GROUP: III. HAZARD LABEL: FLAMMABLE LIQUID. OCEAN
SHIPMENTS: FOR INNER CONTAINERS OF 5L OR LESS USE ONLY AKZO NOBEL
OR UN SPECIFICATION CONTAINERS. POSITIVELY CLOSE ALL SEAMS. FOR
CONTAINERS OF OVER 5L USE 1A1 C ONTAINERS. SHIPPER MUST BE (SARA)

SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
NONE. SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED
HEALTH, FIRE HAZARD. SECTION 313 TOXIC CHEMICALS: ETHYLBENZENE,
TOLUENE, XYLENE. TRANSPO RT (CONT):TRAINED & CERTIFIED TO HANDLE
HAZARDOUS MATERIAL IN MARINE TRANSPORT (IMO/IMDG). PROPER SHIPPING
NAME: PAINT. UN ID #: UN1263. PACKAGING GROUP: III. HAZARD LABEL:
FLAMMABLE LIQUID. HAZARD CL ASS/DIVISION: 3.3. IMDG PAGE (ENGLISH
TRANSLATION):3372. MARINE POLLUTANT: NO. AIR SHIPMENTS: PRODUCTS OF
5L OR LESS MUST BE REPACKAGED FOR AIR TRANSPORTATION INTO UN
SPECIFICATION OUTER PACKAGINGS DE SIGNED FOR TRANSPORT BY AIR.
(FED REG)
Federal Regulatory Information:OSHA: THIS PRODUCT IS CONSIDERED
HAZARDOUS UNDER THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD.
WHMIS: B2:D1A; D2A. TSCA STATUS: ALL INGREDIENTS ARE TSCA
REGISTERED. CEPA STATUS: ONE INGREDIENT IS NO T LISTED ON THE DSL
OR NDSL. SARA (CONT): SHIPPER MUST BE TRAINED & CERTIFIED TO SHIP
HAZARDOUS MATERIAL IN AIR TRANSPORTATION (ICAO/IATA). PROPER
SHIPPING NAME: PAINT. HAZARD CLASS OR DIVISION: 3. UN ID#: UN1263.
PACKAGING GROUP: III. HAZARD LABEL: FLAMMABLE LIQUID. PACKAGING
INSTRUCTIONS PASSENGER AIRCRAFT (IATA ENGLISH TRANSLATION):309 OR
Y309. PACKAGING INSTRUCTIONS CARGO AIRCRAFT (IATA ENGLISH
TRANSLATION): 310. (STATE REGS)
State Regulatory Information:PROPOSITION 65: WARNING: THIS PRODUCT
CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFLORNIA TO CAUSE
REPRODUCTIVE TOXICITY: TOLUENE. FED REGS (CONT): SPECIAL
PROVISIONS: A3, A7, A72. ALSO YOU MAY BE A FFECTED BY OTHER
SECTIONS OF THE LAW, DEPENDING ON CHEMICALS & AMOUNTS THAT
INVENTORY AT YOUR LOCATION. TOXICOLOGICAL(CONT): REPRODUCTIVE
TOXICITY: NONE KNOWN. THRESHOLD LIMIT VALUE: NONE ESTABLISHED FOR
THIS PRODUCT. FOR FURTHER TOXICOLOGICAL & EXPOSURE INFO SEE
INGREDIENTS SECTION. GLOVES (CONT): BARRIER CREAMS ARE NOT
SUBSTITUTES FOR FULL PHYSICAL PROTECTION. REFER TO SAFETY EQUIP
SUPPLIER FOR GLOVE RECOMMENDATIONS.